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isothiouronium : ウィキペディア英語版 | isothiouronium In organic chemistry, isothiouronium is a functional group with the formula ()+ (R = alkyl, aryl). The H centres can also be replaced by alkyl and aryl. Structurally, these cations resemble guanidinium cations. The CN2S core is planar and the C-N bonds are short. Salts comprising these anions are typically prepared by alkylation of thiourea: :SC(NH2)2 + RX → ()+X− Hydrolysis of isothiouronium salts gives thiols. :()+X− + NaOH → RSH + OC(NH2)2 + NaX Chelating resins with isothiouronium groups are used to recover mercury and noble metals including platinum from solutions.〔(【引用サイトリンク】 Purolite S920 Isothiouronium Chelating Resin )〕 ==References== 〔
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