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jasmonate
Jasmonate (JA) and its derivatives are lipid-based hormone signals that regulate a wide range of processes in plants, ranging from growth and photosynthesis to reproductive development. In particular, JAs are critical for plant defense against herbivory and plant responses to poor environmental conditions and other kinds of abiotic and biotic challenges. Some JAs can also be released as volatile organic compounds (VOCs) to permit communication between plants in anticipation of mutual dangers. The isolation of methyl jasmonate from jasmine oil derived from ''Jasminum grandiflorum'' led to the discovery of the molecular structure of jasmonates and their name. == Chemical structure ==
Jasmonates (JA) are an oxylipin, or oxygenated fatty acid, synthesized from linolenic acid residing in chloroplast membranes. Synthesis is initiated with the conversion of linolenic acid to 12-oxo-phytodienoic acid (OPDA), which then undergoes a reduction and three rounds of oxidation to form (+)-7-iso-JA, jasmonic acid proper. Only the conversion of linolenic acid to OPDA occurs in the chloroplast; all subsequent reactions occur in the peroxisome. JA itself can be further metabolized into active or inactive derivatives. Methyl JA (MeJA) is a volatile compound that is potentially responsible for interplant communication. JA conjugated with amino acid isoleucine (Ile) results in JA-Ile, which is currently the only known JA derivative needed for JA signaling.〔
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