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kesterite : ウィキペディア英語版
kesterite

Kesterite is a sulfide mineral with a formula Cu2(Zn,Fe)SnS4. In its lattice structure, zinc and iron atoms share the same lattice sites. Kesterite is the Zn-rich variety whereas the Zn-poor form is called ferrokesterite or stannite. Owing to their similarity, kesterite is sometimes called isostannite.〔 The synthetic form of kesterite is abbreviated as CZTS (from copper zinc tin sulfide). The name kesterite is sometimes extended to include this synthetic material and also CZTSe, which contains selenium instead of sulfur.〔Ingrid Repins, Nirav Vora, Carolyn Beall,
Su-Huai Wei, Yanfa Yan, Manuel Romero, Glenn Teeter, Hui Du, Bobby To, Matt Young, and Rommel Noufi. "(Kesterites and Chalcopyrites: A Comparison of Close Cousins" ) Presented at the 2011 Materials Research Society Spring Meeting
San Francisco, California, April 25–29, 2011 NREL Preprint〕
==Occurrence==
It was first described in 1958 for an occurrence in the Kester deposit (and the associated localilty) in Yana basin, Yakutia, Russia, where it was discovered.〔〔〔
It is usually found in quartz-sulfide hydrothermal veins associated with tin ore deposits.〔 Associated minerals include arsenopyrite, stannoidite, chalcopyrite, chalcocite, sphalerite and tennantite.〔
Stannite and kesterite occur together in the Ivigtut cryolite deposit of South Greenland. Solid solution was found to exist between Cu2FeSnS4 and Cu2ZnSnS4 at temperatures above 680 °C. This accounts for the exsolved kesterite in stannite found in the cryolite.〔S Karup-Møller, ''Galena and Associated Ore Minerals from the Cryolite at Ivigtut, South Greenland,'' Commission for Scientific Research in Greenland, 1979, pp. 8-9 ISBN 978-87-17-02582-0〕

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