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lactide : ウィキペディア英語版
lactide

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Lactide is the cyclic di-ester of lactic acid, i.e., 2-hydroxypropionic acid. Lactic acid cannot form a lactone as other hydroxy acids do because the hydroxy group is too close to the carboxylic group. Instead, lactic acid first forms a dimer, which is similar to a 5-hydroxyacid. The dimer contains a hydroxy group at a convenient distance from the carboxylic group for the formation of a lactone. Indeed, the dimer readily forms a six-membered cyclic diester known as lactide. Lactides may be prepared by heating lactic acid in the presence of an acid catalyst.
In general, a lactide is the cyclic diester, i.e., the di-lactone of two molecules of any 2-hydroxycarboxylic acid.
==Stereoisomers==
Lactic acid is chiral; two enantiomeric forms, (''R'')-lactic acid and (''S'')-lactic acid, may exist. Thus, lactide formed from two equivalents of lactic acid consists of two stereocenters. Three different stereoisomers of lactide are known:

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