|
In organic chemistry, a lactol is the cyclic equivalent of a hemiacetal or a hemiketal. The compound is formed by the intramolecular nucleophilic addition of a hydroxyl group to the carbonyl group of an aldehyde or a ketone. 〔IUPAC Gold Book (lactols )〕 A lactol is often found as an equilibrium mixture with the corresponding hydroxyaldehyde. The equilibrium can favor either direction depending on ring size and other conformational effects. : The lactol functional group is prevalent in nature as component of aldose sugars. ==Chemical reactivity== Lactols can participate in a variety of chemical reactions including: * Oxidation to form lactones * Reaction with alcohols to form acetals * * The reaction of sugars with alcohols or other nucleophiles leads to the formation of glycosides * Reduction (deoxygenation) to form cyclic ethers 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「lactol」の詳細全文を読む スポンサード リンク
|