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lewisite : ウィキペディア英語版
lewisite

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Lewisite is an organoarsenic compound. It was once manufactured in the U.S., Japan, and Germany〔(A drop in the ocean: the sea-dumping of chemical weapons in Okinawa | The Japan Times )〕 for use as a chemical weapon, acting as a vesicant (blister agent) and lung irritant. Although colorless and odorless, impure samples of lewisite are a yellow or brown liquid with a distinctive odor that has been described as similar to geraniums.〔
==Chemical reactions==
The compound is prepared by the addition of arsenic trichloride to acetylene in the presence of a suitable catalyst:
:AsCl3 + C2H2 → ClCHCHAsCl2 (Lewisite)
Lewisite, like other arsenous chlorides, hydrolyses in water to form hydrochloric acid:
:ClCHCHAsCl2 + 2 H2O → ClCHCHAs(OH)2 + 2 HCl
This reaction is accelerated in alkaline solutions, with an arsenic salt being the co-product.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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