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methanethiol : ウィキペディア英語版
methanethiol

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Methanethiol (also known as methyl mercaptan) is an organosulfur compound with the chemical formula . It is a colorless gas with a distinctive putrid smell. It is a natural substance found in the blood and brain of humans and other animals as well as plant tissues. It is disposed of through animal feces. It occurs naturally in certain foods, such as some nuts and cheese. It is also one of the main compounds responsible for bad breath and the smell of flatus. Methanethiol is classified as a thiol and is sometimes abbreviated as MeSH. It is very flammable.
== Structure and reactions ==
The molecule is tetrahedral at carbon, like methanol. It is a weak acid, with a pKa of ~10.4, but is about a million times more acidic than methanol. The colorless salt can be obtained in this way:
: CH3SH + CH3ONa → CH3SNa + CH3OH
The resulting thiolate anion is a strong nucleophile.
It can be oxidized to dimethyl disulfide:
: 2CH3SH + () → CH3SSCH3 + H2O
Further oxidation takes the disulfide to methanesulfonic acid, the latter being odorless. Bleach deodorizes methanethiol in this way.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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