|
| Section2 = }} An oxazolidine is a five-membered ring compound consisting of three carbons, a nitrogen, and an oxygen. The oxygen and NH are the 1 and 3 positions, respectively. In oxazolidine derivatives, there is always a carbon between the oxygen and the nitrogen (or it would be an ''isoxazolidine'').〔Dr Neil G Carter (OXAZOLIDINE DILUENTS: REACTING FOR THE ENVIRONMENT ) Industrial Copolymers Limited〕 All of the carbons in oxazolidines are reduced (compare to oxazole and oxazoline). Some of their derivatives, the oxazolidinediones, are used as anticonvulsants. ==Bisoxazolidines== Bisoxazolidines are chemical compounds that contain two oxazolidine rings, they are used as performance modifiers in polyurethane coatings and paints. The rings hydrolyze in the presence of moisture to give amine and hydroxyl groups, these can then react with diisocyanates to form a coating.〔 (Emission control ) chembytes e-zine 2001.〕 The use of a bisoxazolidine in a polyurethane systems can prevent the unwanted reaction between isocyanate and moisture resulting in coating defects, a result of carbon dioxide release. This moisture triggered curing route is preferential to moisture cure. The choice of linker between the two oxazolidine rings has a large impact on the performance when used to cure isocyanates. A rigid linker group increases a polyurethanes toughness. A flexible linker group imparts flexibility and increases elongation of a coating. These differences are the reason why bisoxazolidines are used to enhance the performance of polyurethane systems. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「oxazolidine」の詳細全文を読む スポンサード リンク
|