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peroxydisulfate : ウィキペディア英語版
peroxydisulfate

The peroxydisulfate ion, S2O82−, is a oxyanion. It is commonly referred to as the persulfate ion, but this term also refers to the peroxomonosulfate ion, SO52−. Approximately 500,000 tons of salts containing this anion are produced annually. Important salts include sodium persulfate (Na2S2O8), potassium persulfate (K2S2O8), and ammonium persulfate ((NH4)2S2O8). These salts are colourless, water-soluble solids that are strong oxidants.
==Applications==
Salts of peroxydisulfate are mainly used to initiate the polymerization of various alkenes, including styrene, acryonitrile, and fluoroalkenes. Polymerization is initiated by the homolysis of the peroxydisulfate:
:: ()2− \overrightarrow 2 ()•
In addition to its major commercial applications, peroxydisulfate participates in reactions of interest in the laboratory:
* Elbs persulfate oxidation
* Oxidation of Ag+ to Ag2+

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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