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phenylphosphine : ウィキペディア英語版
phenylphosphine

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Phenylphosphine is an organophosphorus compound with the chemical formula C6H5PH2. It is the phosphorus analog of aniline. Like other primary phosphines, phenylphosphine has an intense penetrating odor and is highly oxidizable. It is mainly used as a precursor to other organophosphorus compounds. It can function as a ligand in coordination chemistry.〔Svara, Jürgen; Weferling, Norbert ; Hofmann, Thomas "Phosphorus Compounds, Organic" in Ullmann's Encyclopedia of Industrial Chemistry. John Wiley & Sons, Inc, 2008. 〕
==Synthesis==
Phenylphosphine can be produced by reducing dichlorophenylphosphine with lithium aluminum hydride in ether:
:LiAlH4 + 2C6H5PCl2 → 2C6H5PH2 + Li+ + Al3+ + 4Cl
This reaction is performed under a nitrogen atmosphere to prevent side reactions involving oxygen.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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