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phosgene : ウィキペディア英語版
phosgene

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Phosgene is the chemical compound with the formula COCl2. This colorless gas gained infamy as a chemical weapon during World War I where it was responsible for about 85% of the 100,000 deaths caused by chemical weapons. It is also a valued industrial reagent and building block in synthesis of pharmaceuticals and other organic compounds. In low concentrations, its odor resembles freshly cut hay or grass.〔(CBRNE - Lung-Damaging Agents, Phosgene ) May 27, 2009〕 In addition to its industrial production, small amounts occur naturally from the breakdown and the combustion of organochlorine compounds, such as those used in refrigeration systems. The chemical was named by combining the Greek words 'phos' (meaning light) and genesis (birth); it does not mean it contains any phosphorus (cf. phosphine).
==Structure and basic properties==
Phosgene is a planar molecule as predicted by VSEPR theory. The C=O distance is 1.18 Å, the C—Cl distance is 1.74 Å and the Cl—C—Cl angle is 111.8°. It is one of the simplest acid chlorides, being formally derived from carbonic acid.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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