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saponin
Saponins are a class of chemical compounds found in particular abundance in various plant species. More specifically, they are amphipathic glycosides grouped phenomenologically by the soap-like foaming they produce when shaken in aqueous solutions, and structurally by having one or more hydrophilic glycoside moieties combined with a lipophilic triterpene derivative.
==Structural variety and biosynthesis==
The aglycone (glycoside-free) portions of the saponins are termed sapogenins. The number of saccharide chains attached to the sapogenin/aglycone core can varygiving rise to another dimension of nomenclature (monodesmosidic, bidesmosidic, etc.〔)as can the length of each chain. A somewhat dated compilation has the range of saccharide chain lengths being 1–11, with the numbers 2-5 being the most frequent, and with both linear and branched chain saccharides being represented.〔 Dietary monosaccharides such as D-glucose and D-galactose are among the most common components of the attached chains.〔
The lipophilic aglycone can be any one of a wide variety of polycyclic organic structures originating from the serial addition of 10-carbon (C10) terpene units to compose a C30 triterpene skeleton,〔(【引用サイトリンク】title=Project Summary: Functional Genomics of Triterpene Saponin Biosynthesis in Medicago Truncatula )〕 often with subsequent alteration to produce a C27 steroidal skeleton.〔 The subset of saponins that are steroidal have been termed saraponins;〔 Aglycone derivatives can also incorporate nitrogen, so some saponins also present chemical and pharmacologic characteristics of alkaloid natural products. The figure at right above presents the structure of the alkaloid phytotoxin solanine, a monodesmosidic, branched-saccharide steroidal saponin. (The lipophilic steroidal structure is the series of connected six- and five-membered rings at the right of the structure, while the three oxygen-rich sugar rings are at left and below. Note the nitrogen atom inserted into the steroid skeleton at right.)
抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』
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