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tetrabromomethane : ウィキペディア英語版
tetrabromomethane

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Tetrabromomethane, CBr4, also known as carbon tetrabromide, is a carbon bromide. Both names are acceptable under IUPAC nomenclature.
==Physical properties==
Tetrabromomethane has two polymorphs: crystalline II or β below 46.9 °C (320.0 K) and crystalline I or α above 46.9 °C. Monoclinic polymorph has space group ''C2/c'' with lattice constants: ''a'' = 20.9, ''b'' = 12.1, ''c'' = 21.2 (.10−1 nm), β = 110.5°.〔F. Brezina, J. Mollin, R. Pastorek, Z. Sindelar. ''Chemicke tabulky anorganickych sloucenin'' (''Chemical tables of inorganic compounds''). SNTL, 1986.〕 Bond energy of C-Br is 235 kJ.mol−1.〔N. N. Greenwood, A. Earnshaw. ''Chemie prvku'' (''Chemistry of the Elements''). Informatorium, Prague, 1993.〕
Due to its symmetrically substituted tetrahedral structure, its dipole moment is 0 Debye. Critical temperature is 439 °C (712 K) and critical pressure is 4.26 MPa.〔

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