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toluidine
There are three isomers of toluidine, which are organic compounds. These isomers are ''o''-toluidine, ''m''-toluidine, and ''p''-toluidine. The ''o''- stands for ''ortho''-, ''m''- stands for ''meta''- , and ''p''- stands for ''para''- . All three are aryl amines whose chemical structures are similar to aniline except that a methyl group is substituted onto the benzene ring. The difference between these three isomers is the position where the methyl group (-CH3) is bonded to the ring relative to the amino functional group (-NH2); see illustration of the chemical structures below.〔Joseph S. Bowers, "Toluidines" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005. 〕
The chemical properties of the toluidines are quite similar to those of aniline, and toluidines have properties in common with other aromatic amines. Due to the amino group bonded to the aromatic ring, the toluidines are weakly basic. The toluidines is poorly soluble in pure water but dissolve well in acidic water due to formation of ammonium salts, as usual for organic amines. ''ortho''- and ''meta''-Toluidines are viscous liquids, but ''para''-toluidine is a flaky solid. This difference is related to the fact that the ''p''-toluidine molecules are more symmetrical. ''p''-Toluidine can be obtained from reduction of ''p''-nitrotoluene. ''p''-Toluidine reacts with formaldehyde to form Tröger's base.
==Uses and occurrence==
The ortho isomer is produced on the largest scale. Its primary application is as a precursor to the pesticides metolachlor and acetochlor.〔 The other toluidine isomerss are used in the production of dyes. They are a component of accelerators for cyanoacrylate glues.
In some patients o-toluidine is a metabolite of prilocaine, which may cause methemoglobinemia. This is then treated with methylene blue.
抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』
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