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triazane : ウィキペディア英語版
triazane

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Triazane (also systematically named 1,1,2,3,3-pentahydrido-1,2,3-triazy-()catena), or aminohydrazine is an inorganic compound with the chemical formula (also written or ).〔(IUPAC Goldbook )〕 Triazane is the third simplest acyclic azane (the simplest are ammonia and hydrazine). It can be synthesised from hydrazine but is unstable and cannot be isolated in the free base form, only as salt forms such as triazanium sulfate. Attempts to convert triazanium salts to the free base release only diazene and ammonia.
〔Wiberg, Holleman & Wiberg. Inorganic Chemistry. p 627. ISBN 9780123526519〕 Triazane was first synthesised as a ligand of the silver complex ion: tris(μ2-triazane-κ2''N''1,''N''3)disilver(2+).
Several compounds, containing the triazane skeleton are currently known, one such notable compound is 1-methyl-1-nitrosohydrazine, produced from the solventless reaction of methylhydrazine and an alkyl nitrite:
: + → + RHO
1-Methyl-1-nitrosohydrazine is colourless solid, sensitive to impact, but not friction sensitive, and melts at 45°C before decomposing at 121°C. Compared to trinitrotoluene, this compound is more impact sensitive, but less friction sensitive.
==References==


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