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trinitrotriazine : ウィキペディア英語版
trinitrotriazine

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Trinitrotriazine, or 2,4,6-trinitro-1,3,5-triazine, is a theoretical explosive compound. Synthesis of this compound has been elusive despite its simple structure,〔G. D. Hartman, R. D. Hartman and J. E. Schwering. ''Tetrahedron Letters''. 1983; 24: 1011.〕〔M. D. Coburn, C. L. Coon, H. H. Hayden and A. R. Mitchell. ''Synthesis''. 1986: 490.〕 as conventional nitration of triazine becomes increasingly more difficult as more nitro groups are added. A successful route would more likely proceed by trimerisation of nitryl cyanide.〔Korkin AA. Bartlett RJ. Theoretical Prediction of 2,4,6-Trinitro-1,3,5-triazine (TNTA). A New, Powerful, High-Energy Density Material? ''Journal of the American Chemical Society''. 1996; 118: 12244-12245.〕 The precursor, nitryl cyanide has finally been synthetized.〔Rahm, M., Bélanger-Chabot, G., Haiges, R. and Christe, K. O. (2014), Nitryl Cyanide, NCNO2. Angew. Chem. Int. Ed., 53: 6893–6897〕
It has a perfect oxygen balance, potentially making it a very powerful explosive, though calculations predict it would be fairly unstable and inferior to the related compound 3,6-dinitro-1,2,4,5-tetrazine.〔Jinshan Li. An Ab Initio Theoretical Study of 2,4,6-Trinitro-1,3,5-Triazine, 3,6-Dinitro-1,2,4,5-Tetrazine, and 2,5,8-Trinitro-Tri-s-Triazine. ''Propellants, Explosives, Pyrotechnics.'' December 2008; 33(6):443-447.〕
==See also==

* RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine)

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
ウィキペディアで「trinitrotriazine」の詳細全文を読む



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