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・ *aaS
・ (S)-2-hydroxy-acid oxidase
・ (S)-2-hydroxy-fatty-acid dehydrogenase
・ (S)-2-hydroxypropylphosphonic acid epoxidase
・ (S)-2-methylmalate dehydratase
・ (S)-3-amino-2-methylpropionate transaminase
・ (S)-3-hydroxyacid-ester dehydrogenase
・ (S)-6-hydroxynicotine oxidase
・ (S)-beta-bisabolene synthase
・ (S)-beta-macrocarpene synthase
・ (S)-canadine synthase
・ (S)-carnitine 3-dehydrogenase
・ (S)-cheilanthifoline synthase
・ (S)-coclaurine-N-methyltransferase
・ (S)-hydroxynitrile lyase
(S)-iPr-PHOX
・ (S)-Ipsdienol
・ (S)-limonene 3-monooxygenase
・ (S)-limonene 6-monooxygenase
・ (S)-limonene 7-monooxygenase
・ (S)-mandelate dehydrogenase
・ (S)-methylmalonyl-CoA hydrolase
・ (S)-N-acetyl-1-phenylethylamine hydrolase
・ (S)-norcoclaurine synthase
・ (S)-scoulerine 9-O-methyltransferase
・ (S)-squalene-2,3-epoxide hydro-lyase
・ (S)-stylopine synthase
・ (S)-sulfolactate dehydrogenase
・ (S)-tetrahydroprotoberberine N-methyltransferase
・ (S)-usnate reductase


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(S)-iPr-PHOX : ウィキペディア英語版
(S)-iPr-PHOX

(''S'')-iPr-PHOX, or (''S'')-2-()-4-isopropyl-4,5-dihydrooxazole, is a chiral, bidentate, ligand derived from the amino alcohol valinol. It is part of a broader class of phosphinooxazolines ligands and has found application in asymmetric catalysis.
==Preparation==
(''S'')-iPr-PHOX is prepared using the amino alcohol valinol, which is derived from valine. The phosphine moiety may be introduced first, by a reaction between 2-bromobenzonitrile and chlorodiphenylphosphine; the oxazoline ring is then formed in a Witte Seeliger reaction. This yields an air stable zinc complex which must be treated with bipyridine in order to obtain the free ligand. Synthesis is performed under argon or nitrogen to avoid contact with air, however the final product is not air sensitive.
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