翻訳と辞書 Words near each other ・ 1,3-Propanediol ・ 1,3-propanediol dehydrogenase ・ 1,3-Propanedithiol ・ 1,3-Thiazepine ・ 1,4,2-Dithiazole ・ 1,4,6-Androstatriene-3,17-dione ・ 1,4,7-Triazacyclononane ・ 1,4,7-Trithiacyclononane ・ 1,4-a-glucan 6-a-glucosyltransferase ・ 1,4-Benzodioxine ・ 1,4-Benzoquinone ・ 1,4-beta-D-xylan synthase ・ 1,4-Butanediol ・ 1,4-Butynediol ・ 1,1,1-Trifluoroethane ・ 1,1,1-Tris(aminomethyl)ethane ・ 1,1,2,2,3,3-Hexachloropropane ・ 1,1,2,2-Tetrachloroethane ・ 1,1,2-Trichloro-1,2,2-trifluoroethane ・ 1,1,2-Trichloroethane ・ 1,1,3,3-Tetramethylguanidine ・ 1,1,3-Trichloropropene ・ 1,1-Bis(diphenylphosphino)methane ・ 1,1-Dibromoethane ・ 1,1-Dichloro-1-fluoroethane ・ 1,1-Dichloroethane ・ 1,1-Dichloroethene ・ 1,1-Diethoxyethane ・ 1,1-Difluoroethane ・ 1,1-Difluoroethylene Dictionary Lists mini英和辞書 mini和英辞書 Webster 1913 Latin-English FOLDOC Wikipedia English ウィキペディア

翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク 1,1,1-Tris(aminomethyl)ethane ： ウィキペディア英語版 1,1,1-Tris(aminomethyl)ethane 1,1,1-Tris(aminomethyl)ethane (TAME) is an organic compound with the formula CH3C(CH2NH2)3. It is a colorless liquid. It is classified as a polyamine tripodal ligand, i.e., capable of binding to metal ions through three sites and hence is a tridentate chelating ligand, occupying a face of the coordination polyhedron. ==Preparation== TAME is synthesized by the Pd/C-catalyzed hydrogenation of 1,1,1-tris(azidomethyl)ethane. Although azides are potentially explosive, they are excellent and practical source of primary amines. The required tris(azidomethyl)ethane is obtained from the tritosylate by salt metathesis using sodium azide. These two steps are:〔L. J. Zompa and J.-P. Anselme, "Catalytic Reduction of 1,1,1 tris(azidomethyl)ethane to 1,1,1 tris(Aminomethyl)ethane" Org. Prep. Proced. lnt, 6, 103 (1974).〕 :3 NaN3 + CH3C(CH2OTs)3 → CH3C(CH2N3)3 + 3 NaOTs :3 H2 + CH3C(CH2N3)3 → CH3C(CH2NH2)3 + 3 N2 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「1,1,1-Tris(aminomethyl)ethane」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.